We report a trap-assisted photomultiplication (PM) phenomenon in solution-processed polymer photodetectors (PPDs) based on P3HT:PC 71BM as the active layer, the maximum EQE of 16,700% is obtained for the PPDs with PC 71BM doping weight ratio of 1%. The PM phenomenon is attributed to the enhanced hole tunneling injection assisted by trapped electrons in PC 71BM near Al cathode, which can be demonstrated by the transient photocurrent curves and EQE spectra of PPDs with different PC 71BM doping ratios.
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